Operability analysis is one of the bridges that links process design and co
ntrol. In this paper, we analyze the steady-state operability characteristi
cs of classical reactors (CSTR and PER) in the framework of Vinson and Geor
gakis (DYCOPS-5. Fifth IFAC Symposium on Dynamics and Control of Process Sy
stems. 1998, pp. 700-709, J, Proc. Control 10 (2000) 185). Reaction schemes
vary from simple first-order A --> B to industrially relevant competing re
actions. The nonlinear nature of reactors requires the use of special compu
tational techniques for the determination of the operability index (OI). Th
is study clearly brings out the potential of the OI framework. In addition
to measuring the servo, regulatory, and overall operability of the systems
studied. we were able to identify safe operating regions and tolerable dist
urbances with the available inputs. This analysis also points to optimized
process conditions. (C) 2001 Elsevier Science Ltd. All rights reserved.