Redox-activity in complexes with Mo(NO) and Mo(O) cores: Facts and consequences

Authors
McCleverty, JA Ward, MD Jones, CJ
Citation
Ja. Mccleverty et al., Redox-activity in complexes with Mo(NO) and Mo(O) cores: Facts and consequences, COMM INOR C, 22(5), 2001, pp. 293-326
Citations number
74
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
COMMENTS ON INORGANIC CHEMISTRY
ISSN journal
02603594 → ACNP
Volume
22
Issue
5
Year of publication
2001
Pages
293 - 326
Database
ISI
SICI code
0260-3594(2001)22:5<293:RICWMA>2.0.ZU;2-D
Abstract
A series of mono, di-, tri- and tetranuclear nitrosyl and oxo molybdenum co mplexes containing the tris(3,5-dimethylpyrazolyl)borato ligand exhibit a r ange of redox processes which are controlled mainly by the ligands and by t he extent of oligonucleation. Homo- and hetero-dinuclear complexes have a r ange of properties dependent on this redox behaviour, and linear (electroch romism in the near infrared) and non-linear (second harmonic generation) pr operties are described.