A one-dimensional mathematical model was developed for the simulation of pe
troleum coke calcination in rotary kilns. The model is comprised of 14 ordi
nary differential equations derived from mass and energy conservation princ
iples. The system of equations is solved by a fourth-order Runge-Kutta meth
od. The model predicts, in the axial direction, temperature profiles for th
e bed of particles, the gas phase and the kiln internal wall. It also predi
cts the composition profiles for the gas and solid phases. The modeling of
the axial flow of the bed includes the rheological characteristics of the p
articulate system. The results from the simulation of the calcination syste
ms presented better agreement with measured industrial data than other simu
lation results available in the literature. (C) 2001 Published by Elsevier
Science Ltd.