Beckmann rearrangement of cyclohexanone oxime over modified molecular sieves

Authors
Murthy, KVVSBSR Chandrakala, M Kulkarni, SJ Raghavan, KV
Citation
Kvvsbsr. Murthy et al., Beckmann rearrangement of cyclohexanone oxime over modified molecular sieves, I J CHEM T, 8(5), 2001, pp. 368-370
Citations number
11
Categorie Soggetti
Chemical Engineering
Journal title
INDIAN JOURNAL OF CHEMICAL TECHNOLOGY
ISSN journal
0971457X → ACNP
Volume
8
Issue
5
Year of publication
2001
Pages
368 - 370
Database
ISI
SICI code
0971-457X(200109)8:5<368:BROCOO>2.0.ZU;2-C
Abstract
The vapour phase Beckmann rearrangement of cyclohexanone oxime to epsilon - Caprolactum over silicoaluminophosphate (MSAPO-5, MSAPO-11) and MZSM-5 has been carried out. The yields of epsilon -Caprolactum were 72.0 and 81.5% at 96.0 and 100% conversion over ZnSAPO-11 and TiSAPO-11 molecular sieves, re spectively.