Synthesis and properties of binuclear copper(II) complex - Oxidative addition reaction

Authors
Yang, RN Yang, HF Wang, DM Liu, YF Jin, DM
Citation
Rn. Yang et al., Synthesis and properties of binuclear copper(II) complex - Oxidative addition reaction, I J CHEM A, 40(9), 2001, pp. 979-982
Citations number
11
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
9
Year of publication
2001
Pages
979 - 982
Database
ISI
SICI code
0376-4710(200109)40:9<979:SAPOBC>2.0.ZU;2-B
Abstract
At room temperature, dibenzoyl peroxide undergoes oxidative addition reacti on with metallic copper powder and quinoline to afford the binuclear copper (II) complex, [CU(C6H5COO)(2)-(C9H7N)](2). This complex is further characte rized by physicochemical and spectroscopic methods. The structure of the co mplex has been determined by a single-crystal X-ray analysis. Each copper(I I) ion is coordinated by two bridging bidentate benzoate and quinoline to f orm dimeric molecule.