Homolytic displacements at carbon in organocobaloximes: Reactions of organocobaloximes with free radical precursor with two radical centres

Authors
Gupta, BD Oberoi, M Mandal, D Tiwari, U Yamuna, R Kanth, VV Singh, V
Citation
Bd. Gupta et al., Homolytic displacements at carbon in organocobaloximes: Reactions of organocobaloximes with free radical precursor with two radical centres, I J CHEM A, 40(9), 2001, pp. 986-988
Citations number
22
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
9
Year of publication
2001
Pages
986 - 988
Database
ISI
SICI code
0376-4710(200109)40:9<986:HDACIO>2.0.ZU;2-L
Abstract
The reactions Of MeC6H4-SO2-SPh with organocobaloximes, RCo(dingH)(2)Py, (R = alkyl, benzyl, butenyl and allyl) under visible light photolysis show th at the alkyl, butenyl and benzyl cobaloximes form the corresponding sulphid es whereas the allyl cobaloximes form the organic sulphones.