beta ''-(BEDT-TTF)(4)](H3O)Cr(C2O4)(3)]CH2Cl2: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt

Authors
Rashid, S Turner, SS Le Pevelen, D Day, P Light, ME Hursthouse, MB Firth, S Clark, RJH
Citation
S. Rashid et al., beta ''-(BEDT-TTF)(4)](H3O)Cr(C2O4)(3)]CH2Cl2: Effect of included solvent on the structure and properties of a conducting molecular charge-transfer salt, INORG CHEM, 40(20), 2001, pp. 5304
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
20
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010924)40:20<5304:B'EOIS>2.0.ZU;2-3
Abstract
The new charge-transfer salt beta "-(BEDT-TTF)(4)[(H3O)Cr(C2O4)(3)]S, where BEDT-TTF = bis(ethylenedithio)tetrathiaful valene and S = CH2Cl2, has a br oad metal-insulator transition at approximately 150 K. This differs from si milar salts in the BEDT-TTF tris(oxalato) metalate Series, notably the supe rconducting materials with S = PhCN and the salt with S = C5H5N, which has a sharp metal-insulator transition. GRAPHICS.