Complexation of a heptanuclear polyoxotantalate anion with K+: Formation of a supramolecular [K-6-(mu-OH2)(6)-(OH2)(8)](6+) ring structure

Authors
Morgenstern, B Sander, J Huch, V Hegetschweiler, K
Citation
B. Morgenstern et al., Complexation of a heptanuclear polyoxotantalate anion with K+: Formation of a supramolecular [K-6-(mu-OH2)(6)-(OH2)(8)](6+) ring structure, INORG CHEM, 40(20), 2001, pp. 5307
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
20
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010924)40:20<5307:COAHPA>2.0.ZU;2-#
Abstract
Complexation of a Heptanuclear Polyoxotantalate Anion with K+: Formation of a Supramolecular [K-6-(mu -OH2)(6)-(OH2)(8)](6+) Ring Structure Hydrolysis of Ta-V in the presence of KOH and cis-inositol (ino) resulted in the form ation of the heptanuclear polyoxotantalate anion [Ta7O12(H(-3)ino)(6)](-7) with a double adamantane core: its structure is stabilized by a surrounding [K-6-(mu -OH2)(6)-(OH2)(8)](6+) ring.