Reactions of chloride iron(II) clathrochelates with aliphatic amines: an unexpected influence of the nature of the amine and solvent on the reaction products

Authors
Voloshin, YZ Zavodnik, VE Varzatskii, OA Belsky, VK Vorontsov, II Antipin, MY
Citation
Yz. Voloshin et al., Reactions of chloride iron(II) clathrochelates with aliphatic amines: an unexpected influence of the nature of the amine and solvent on the reaction products, INORG CHIM, 321(1-2), 2001, pp. 116-134
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
321
Issue
1-2
Year of publication
2001
Pages
116 - 134
Database
ISI
SICI code
0020-1693(20010910)321:1-2<116:ROCICW>2.0.ZU;2-8
Abstract
The interaction of the reactive di- and hexachloride clathrochelate iron(II ) precursors with primary and secondary aliphatic amines of different natur e in a wide range of donor and acceptor solvents has been studied. The part ially functionalized aminic clathrochelates obtained have been characterize d using elemental analysis, PD mass, IR, UV-Vis, Fe-57 Mossbauer and H-1, C -13 NMR spectra and crystallographically (Fe((C6H11NH)2Gm)(Cl2Gm)(BC6H5)2 . n-C5H12 and Fe((n-C4H9NH)ClGm)(Cl2Gm)(2)-(BC6)H-5)(2) complexes). The cause s of an unexpected influence both amine and solvent nature on the product o f reaction with chloride clathrochelate precursors have been discussed. (C) 2001 Elsevier Science BN. All rights reserved.