Synthesis and structural characterisation of [RuCl(NO)(eta(2)-O-2)(PPh3)(2)]

Authors
Morales-Morales, D Redon, R Cramer, RE
Citation
D. Morales-morales et al., Synthesis and structural characterisation of [RuCl(NO)(eta(2)-O-2)(PPh3)(2)], INORG CHIM, 321(1-2), 2001, pp. 181-184
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
321
Issue
1-2
Year of publication
2001
Pages
181 - 184
Database
ISI
SICI code
0020-1693(20010910)321:1-2<181:SASCO[>2.0.ZU;2-8
Abstract
The extremely reactive and air-sensitive nitrosyl-ruthenium(0) species tran s-[RuCl(NO)(PPh3)(2)] (2) oxidatively adds HCl to give the octahedral ruthe nium(II) complex [RuHCl2(NO)(PPh3)(2)] (3). On treatment of 2 with O-2, the five-coordinate 1:1 adduct [RuCl(NO)(eta (2)-O-2)(PPh3)(2)] (4) is formed. The dioxygen complex has been characterised by X-ray structural analysis. (C) 2001 Elsevier Science B.V. All rights reserved.