Nanophased ZrO2-CeO2 or TiO2-ZrO2-CeO2 films by CVD as catalysts for hydrocarbon complete combustion

Growths of nanophased ZrO2-CeO2 or TiO2-ZrO2-CeO2 thin films, interesting a s catalysts for complete oxidation of hydrocarbons, were performed by using cerium tetrakis-2,2,6,6-tetramethyl-3,5-heptanedionate, zirconium tris-iso propoxy 2,2,6,6-tetramethyl-3,5-heptanedionate and titanium tetraisopropoxi de as CVD precursors at a reactor temperature of 380 degreesC. Alumina glas s and honeycomb cordierite were used as substrates. Two different approache s were proposed in order to obtain composite oxide films: a sequential depo sition of single-phase coatings and thermal treatment of the final multi-la yers to favour the interdiffusion, or a co-deposition of CeO2 and ZrO2. Bot h crystallization and intermixing behaviour of composite films were studied after annealing in air at 1000 degreesC by X-ray Diffraction, Scanning Ele ctron Microscopy and X-ray Photoelectron Spectroscopy.