We report the first observation of X-ray emission (4 - 18 nm) from small-si
zed Ne clusters heated by high-intensity, 25-100 A laser pulses. The Ne spe
ctrum started to drastically change in emitting ions from Ne5+ to Ne7+ belo
w the pre-expansion temperature of -120 degreesC. The significant change in
the spectrum is attributed to the collisional heating of small-sized Ne cl
usters formed in the cryogenically cooled gas jet. Though the size of Ne cl
usters in our experiment is estimated to be quite small, i.e. a few tens of
atoms per cluster, and thus they were undetectable by the standard Rayleig
h scattering technique, the. appearance of spectral lines of Ne7+ ions pres
ented clear evidence of collisional heating that occurred in near-solid-den
sity cluster. By extending the laser pulse length from 25 fs to 100 fs, con
siderably higher X-ray yield from the highest charge state Ne7+ was observe
d in the covered spectral region, showing more efficient absorption of 100
fs laser pulse.