Elimination of isobaric interferences in ICP-MS, using ion-molecule reaction chemistry: Rb/Sr age determination of magmatic rocks, a case study

It is shown that ion-molecule reactions in a dynamic reaction cell (DRC) al low the Rb-87/Sr-87 isobaric interference to be eliminated and that Sr isot ope ratios can be determined precisely and accurately by measuring the inte nsities of the corresponding SrF+ ion beams after selective reaction of Sr with CH3F in the cell. The technique is used for the Rb/Sr age determinatio n of magmatic rocks, without any sample pretreatment except for the dissolu tion or the samples. Sr isotope ratios can thus be measured with a precisio n that is very near to counting statistics and the measured age and initial Sr-87/Sr-86 ratio of the rocks fully agrees with reference values of therm al ionisation mass spectrometry (TIMS). The precision of the age is of the same order as the precision of the TIMS results.