Influence of the growth conditions and postdeposition treatments upon the grain boundary barrier height of CdTe thin films deposited by close space vapor transport
O. Vigil-galan et al., Influence of the growth conditions and postdeposition treatments upon the grain boundary barrier height of CdTe thin films deposited by close space vapor transport, J APPL PHYS, 90(7), 2001, pp. 3427-3431
CdTe thin films deposited by close space vapor transport (CSVT) under varia
ble growth conditions and postthermal and chemical treatments were studied
by means of photoconductivity measurements in the temperature range of 90-3
00 K. The influences of the deposition temperature gradient, the oxygen con
tent in the growth chamber, and the CdCl2 treatment and chemical etching up
on the intergrain barrier height of CSVT polycrystalline CdTe thin films we
re determined. The grain boundary barrier height (E-b phi) as a function of
the intensity of the incident light was analyzed, and values of E-b phi un
der illumination of 100 mW/cm(2) (AM1) were obtained in each case. These re
sults are important for improving CdS/CdTe solar cell performance in the ne
ar future. (C) 2001 American Institute of Physics.