V. Taghikhani et al., Liquid-liquid equilibria of water plus propionic acid plus methyl butyl ketone and of water plus propionic acid plus methyl isopropyl ketone, J CHEM EN D, 46(5), 2001, pp. 1107-1109
Liquid-liquid equilibria of water + propionic acid + methyl butyl ketone (2
-hexanone) and of water + propionic acid + methyl isopropyl ketone (3-methy
l-2-butanone) systems were measured at the temperatures (25, 35, and 45) de
greesC. Complete phase diagrams were obtained by determining solubility and
the tie-line data. The reliability of the experimental tie-line data was d
etermined through the Othmer-Tobias plots. Distribution coefficients and se
paration factors were evaluated over the immiscibility regions. It is concl
uded that both methyl butyl ketone and methyl isopropyl ketone are suitable
separating agents for dilute aqueous propionic acid.