RELATIONSHIP BETWEEN THE SURFACE-POTENTIA L AND 2ND-HARMONIC GENERATION IN DOPED POLYVINYLACETATE

Authors
VANNIKOV AV KLASON C MALTSEV EI RYCHWALSKI RW SAVELEV VV
Citation
Av. Vannikov et al., RELATIONSHIP BETWEEN THE SURFACE-POTENTIA L AND 2ND-HARMONIC GENERATION IN DOPED POLYVINYLACETATE, Vysokomolekularnye soedinenia. Seria A, 39(6), 1997, pp. 1038-1042
Citations number
13
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
39
Issue
6
Year of publication
1997
Pages
1038 - 1042
Database
ISI
SICI code
0507-5475(1997)39:6<1038:RBTSLA>2.0.ZU;2-7
Abstract
The intensity of the second-harmonic emission, generated by a laser be am passing through a corona-discharge- polarized film of polyvinylacet ate doped with 4-(dimethyla,mino)-4'-nitrostilbene, was studied as a f unction of the temperature, time, degree of the free volume relaxation , and surface potential. It is established that the second harmonic in tensity decay kinetics is controlled by a decrease in the surface pote ntial with time. Relaxation of the free volume of the polymer modifies the kinetics of the surface potential, thus also affecting the second -harmonic emission intensity.