Field experiments were conducted to determine the oxygenation potential of
gated sill structures in the Ohio River Valley. The objective was to determ
ine operational procedures for water quality improvement. Oxygenation poten
tial is typically characterized by gas transfer efficiency, with high trans
fer efficiency indicating a greater input of oxygen into the water. Direct
oxygen measurement can be unreliable in determining transfer efficiency, an
d this is due to upstream stratification, relatively high background concen
trations, and changes in saturation concentration when the bubbles are expo
sed to hydrostatic pressures within the stilling basin. As a result, in sit
u methane was used as an independent dissolved gas tracer. Methane is natur
ally present in measurable quantities with little stratification, and it do
es not experience an appreciable increase in saturation concentration with
bubble depth. Therefore, methane measurements better reflect the true trans
fer efficiency of a structure. This paper focuses on the factors that influ
ence transfer efficiency and how to achieve high quality field data through
the use of methane and oxygen measurements. In addition, results from six-
gated sill structures in the Ohio River Valley are presented.