The recently discovered phenomenon of potential sputtering, i.e., the
efficient removal of neutral and ionized target particles from certain
insulator surfaces due to the potential rather than the kinetic energ
y of impinging slow highly charged ions, has now also been observed fo
r stoichiometric SiO2 surfaces. Using a sensitive quartz crystal micro
balance technique, total sputter yields induced by Arq+ (q less than o
r equal to 14) and Xeq+ (q less than or equal to 27) ions have been de
termined for LIF and SiO2 surfaces. The primary mechanisms for potenti
al sputtering (defect mediated sputtering) and its considerable practi
cal relevance for highly charged ion-induced surface modification of i
nsulators are discussed.