DENDRIMERS WITH ANTHYRIDINE-BASED HYDROGEN-BONDING UNITS AT THEIR CORES - SYNTHESIS, COMPLEXATION AND SELF-ASSEMBLY STUDIES

Authors
WANG Y ZENG FW ZIMMERMAN SC
Citation
Y. Wang et al., DENDRIMERS WITH ANTHYRIDINE-BASED HYDROGEN-BONDING UNITS AT THEIR CORES - SYNTHESIS, COMPLEXATION AND SELF-ASSEMBLY STUDIES, Tetrahedron letters, 38(31), 1997, pp. 5459-5462
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
31
Year of publication
1997
Pages
5459 - 5462
Database
ISI
SICI code
0040-4039(1997)38:31<5459:DWAHUA>2.0.ZU;2-8
Abstract
Generation 1-4 Frechet-type dendritic bromides were covalently linked to anthyridine (6) to give ''sticky'' dendrons 7a-7d. The binding cons tants of 1:1 complexes between 7 and benzamidinium salt 8 were measure d to assess their ability to act as building blocks for self-assembly. A 2:1 complex of 7 and pentamidine 9 formed in 1% CD3CN/CDCl3 indicat ing the utility of these compounds for constructing larger dendritic a ssemblies. (C) 1997 Elsevier Science Ltd.