(CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings

Authors
Harrison, WTA Phillips, MLF Nenoff, TM
Citation
Wta. Harrison et al., (CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings, J CHEM S DA, (17), 2001, pp. 2459-2461
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
17
Year of publication
2001
Pages
2459 - 2461
Database
ISI
SICI code
1472-7773(20010907):17<2459:(DZAOZ>2.0.ZU;2-E
Abstract
The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the e xtraframework guanidinium cations. The structure is stabilised by template- to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organical ly-templated zinc phosphates.