SKELETAL REARRANGEMENT VIA ALKOXY RADICAL - CONVERSION OF EPOXYDECALIN THIOCARBONYLIMIDAZOLIDE TO BICYCLO[6.3.0]UNDECANONE AND BICYCLO[5.3.1]UNDECANONE

Authors
NISHIDA A KAKIMOTO Y OGASAWARA Y KAWAHARA N NISHIDA M TAKAYANAGI H
Citation
A. Nishida et al., SKELETAL REARRANGEMENT VIA ALKOXY RADICAL - CONVERSION OF EPOXYDECALIN THIOCARBONYLIMIDAZOLIDE TO BICYCLO[6.3.0]UNDECANONE AND BICYCLO[5.3.1]UNDECANONE, Tetrahedron letters, 38(31), 1997, pp. 5519-5522
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
31
Year of publication
1997
Pages
5519 - 5522
Database
ISI
SICI code
0040-4039(1997)38:31<5519:SRVAR->2.0.ZU;2-I
Abstract
The radical reaction of three epoxydecalin thiocarbonylimidazolides wa s investigated using nBu(3)SnH and AIBN. Two types of rearrangement fr om a ten-membered cyclic carbon radical, which was formed by beta-clea vage of alkoxy radicals, were observed. (C) 1997 Elsevier Science Ltd.