Three series of fluorinated bistolane-type liquid crystals have been synthe
sized. Their mesomorphic properties were studied by optical polarizing micr
oscopy and DSC. These compounds exhibit only a broad nematic phase with hig
h clearing points, wide phase transition temperatures and low melting point
s. The effects of lateral fluoro-substitution and the introduction of the t
etrafluorophenylene moiety are discussed in detail.