A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ions in the interlamellar space

Authors
Jayaraman, K Choudhury, A Vaidhyanathan, R Rao, CNR
Citation
K. Jayaraman et al., A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ions in the interlamellar space, NEW J CHEM, 25(9), 2001, pp. 1199-1202
Citations number
30
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
25
Issue
9
Year of publication
2001
Pages
1199 - 1202
Database
ISI
SICI code
1144-0546(200109)25:9<1199:ALCNCN>2.0.ZU;2-4
Abstract
Reaction between CdCl2.H2O and NaH2PO4.H2O Under hydrothermal conditions gi ves rise to a new cadmium chlorophosphate of the formula Na-3[Cd4Cl3(HPO4)( 2)(H2PO4)(4)] I. This material crystallizes in the orthorhombic system with space group Fmm2(no. 42). I has macroanionic layers of [Cd4Cl3(HPO4)(2)(H2 PO4)(4)](3-) with Na+ ions in the interlamellar space. The discovery of suc h compounds suggests that metathetic reactions carried out under hydrotherm al conditions may provide a novel route for the synthesis of new open-frame work structures.