We show that D-mode Raman scattering in single-walled carbon nanotubes is d
ue to a double-resonant Raman process. The unusual shift of the D-mode freq
uency with excitation energy is even expected for a single nanotube. The ma
gnitude of the shift and the D-mode frequency depend strongly on the tube's
diameter and chirality. Only tubes with (n(1)-n(2))/3n integer contribute
to the D-mode spectrum because of the particular electronic structure of ca
rbon nanotubes.