Below the E-0 band gap of GaAs the transitions of free electrons to bound i
mpurity states play an important role. Our study of Raman scattering above
the (e,A(0)) threshold at 2 K shows that the electrons are scattered by aco
ustic phonons before successively being scattered by one LO phonon and fina
lly recombining the holes bound to the acceptors. This finding indicates on
e of important mechanisms of relaxation of the hot electrons excited above
the minimum of conduction band.