In situ Raman study of C-60 thin films at high pressures - art. no. 113408

Raman spectra from a systematic in situ study of C-60 thin films at nonhydr ostatic compression up to 30 GPa are presented in a broad spectral range (2 00-1800 cm(-1)). The results show that the superhard fullerite obtained at 22.5 GPa transforms back to one-dimensional (1D) polymeric phase after quen ching if no heat is added. This suggests that the most likely structure for the superhard fullerite phase is a three-dimensional polymeric structure o f unbroken C-60 molecules. Nevertheless, depolymerization of superhard full erite was not observed if a heat treatment was added. In situ Raman spectra from the heated films were identical to those obtained without heating but the absence of a depolymerization transformation suggest a structural chan ge which cannot be observed in the Raman spectra. A thickness effect was al so observed for the high-pressure transformation. Higher pressures were req uired for the transformation of the thinner films. This was attributed to a decreased dimensionality in the thinner films making a 3D polymerization m ore difficult.