Two-dimensional network of C-H center dot center dot center dot Cl-Co hydrogen bonds in the structure of 1,1,4,4-tetraisopropylpiperazinium tetrachlorocobaltate(II)

Authors
Mahmoudkhani, AH Langer, V Casari, BM
Citation
Ah. Mahmoudkhani et al., Two-dimensional network of C-H center dot center dot center dot Cl-Co hydrogen bonds in the structure of 1,1,4,4-tetraisopropylpiperazinium tetrachlorocobaltate(II), ACT CRYST E, 57, 2001, pp. m393-m395
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
m393 - m395
Database
ISI
SICI code
1600-5368(200109)57:<m393:TNOCCD>2.0.ZU;2-8
Abstract
The reaction of (2-hydroxyethyl)diisopropylammonium chloride with CoCl2. 6H (2)O has resulted in the unusual formation of a quaternary piperazinium sal t with the formula (tippipz)[CoCl4], where tippipz is tetraisopropylpiperaz inium (C16H36N22+). The structure of this compound consists of sheets of or ganic ammonium dications and inorganic dianions formed by C-H . . . Cl hydr ogen bonds.