(Methanol){alpha-5,10,15 :beta-20-tetrakis[2-(chloroacet-amido)phenyl]porphyrin}zinc(II) chloroform solvate

Authors
Ricard, D Richard, P Boitrel, B
Citation
D. Ricard et al., (Methanol){alpha-5,10,15 :beta-20-tetrakis[2-(chloroacet-amido)phenyl]porphyrin}zinc(II) chloroform solvate, ACT CRYST E, 57, 2001, pp. m404-m406
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
m404 - m406
Database
ISI
SICI code
1600-5368(200109)57:<m404:(:>2.0.ZU;2-O
Abstract
The pentacoordinated Zn atom in the title compound, [Zn(C52H36Cl4N8O4)(CH4O )]. CHCl3, is displaced from the porphyrin N-4 plane towards the axial meth anol ligand by 0.269 (2) Angstrom. The average Zn-N(porphyrin) distance is 2.063 (9) Angstrom and the axial Z-DO(MeOH) distance is 2.147 (5) Angstrom.