A tetranuclear copper compound containing three different types of anions:trans-(mu-tert-butoxy)bis(mu-2,4,6,2 '',4 '',6 ''-hexamethyl-1,1 ': 3 ',1 ''-terphenyl-2 ',2 '-diyl)(mu-iodo)tetracopper(I)

Authors
Niemeyer, M
Citation
M. Niemeyer, A tetranuclear copper compound containing three different types of anions:trans-(mu-tert-butoxy)bis(mu-2,4,6,2 '',4 '',6 ''-hexamethyl-1,1 ': 3 ',1 ''-terphenyl-2 ',2 '-diyl)(mu-iodo)tetracopper(I), ACT CRYST E, 57, 2001, pp. m416-M418
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
m416 - M418
Database
ISI
SICI code
1600-5368(200109)57:<m416:ATCCCT>2.0.ZU;2-U
Abstract
The title compound [(CuDmp)(2)(CuI)(CuO'Bu)] (Dmp=2,6-Mes(2)C(6)H(3) with M es = 2,4,6-Me3C6H2), [Cu4I(C4H9O)-(C24H25)(2)], was obtained as by-product of the synthesis of the copper aryl (CuDmp)2. It contains an almost planar central Cu4C2IO ring with two-coordinate Cu atoms and two different sets of Cu-C distances (average Cu-C = 1.952 and 2.032 Angstrom; average Cu-O = 1. 859 Angstrom; average Cu-I = 2.4478 Angstrom).