Hexamethylenediammonium hydrogenphosphite

Citation
Ah. Mahmoudkhani et V. Langer, Hexamethylenediammonium hydrogenphosphite, ACT CRYST E, 57, 2001, pp. o866-o868
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
o866 - o868
Database
ISI
SICI code
1600-5368(200109)57:<o866:HH>2.0.ZU;2-X
Abstract
In the structure of the title compound, C6H18N22+. 2H(2)PO(3)(-),the hexame thylenediammonium dication has a center of symmetry and the asymmetric unit contains half of the dication and one hydrogenphosphite anion. The (PD)OD H . . .O(-P) and N-H . . .O(-P) hydrogen bonds link ammonium and hydrogenph osphite groups to form a two-dimensional hydrogen-bonded network. Layers ar e linked covalently into pillars by bifunctional diammonium moieties, makin g a three-dimensional framework.