L-Aargininium dinitrate

Citation
S. Ramaswamy et al., L-Aargininium dinitrate, ACT CRYST E, 57, 2001, pp. o872-o874
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
o872 - o874
Database
ISI
SICI code
1600-5368(200109)57:<o872:LD>2.0.ZU;2-5
Abstract
In the title compound, C6H16N4O22+. 2NO(3)(-), the diprotonated argininium molecule is linked by a strong O-H . . .O [2.653 (7) Angstrom] hydrogen bon d to the nitrate anion. The single-bonded O atom of the carboxyl group exhi bits a very unusual cis conformation with respect to the alpha -amino N ato m. Chelated three-centered hydrogen bonds are observed in the case of the N -alpha and N-epsilon atoms with the nitrate anions. The argininium molecule s are connected by type A, B and D interactions through nitrate anions.