3-Benzylidene-1 '-methyl-4 '-phenylcyclohexanespiro3 '-pyrrolidine-2 '-spiro-3 ''-indoline-2,2 ''-dione

Citation
A. Jeyabharathi et al., 3-Benzylidene-1 '-methyl-4 '-phenylcyclohexanespiro3 '-pyrrolidine-2 '-spiro-3 ''-indoline-2,2 ''-dione, ACT CRYST E, 57, 2001, pp. o901-O903
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
9
Pages
o901 - O903
Database
ISI
SICI code
1600-5368(200109)57:<o901:3''''>2.0.ZU;2-G
Abstract
In the title compound, C30H28N2O2, there are two molecules in the asymmetri c unit. In both molecules, the pyrrolidine ring adopts an envelope conforma tion whereas the conformation of the cyclohexane ring is half-chair. The ox indole moiety is almost perpendicular to the pyrrolidine ring; the benzylid ene moiety and the phenyl ring are in equatorial and bisectional configurat ions with respect to their attached pyrrolidine and cyclohexanone rings, re spectively. Intramolecular C-H . . .O and intermolecular N-H . . .N and N-H . . .O interactions stabilize the molecular structure and the packing in t he crystal.