W. Chen et al., Poly[[silver(I)-di-mu-1,5-bis(phenylthio)pentane] hexafluorophosphate]: a two-dimensional molecular-rectangle coordination polymer, ACT CRYST E, 57, 2001, pp. M213-m215
In the title Ag I complex of 1,5-bis(phenylthio)pentane, {[Ag(C17H20S2)(2)]
PF6}(n), Ag-I centers coordinate to four S atoms and display a distorted te
trahedral geometry. Ligands link adjacent Ag-I atoms to form an infinite pa
rquet-like framework. The PF6- ions are incorporated in the cavities of the
network to complete and stabilize the structure.