Bis(dimethylglyoximato-N,N ')(ethanol-O)nitrocobalt(III), [Co(Hdmg)(2)(NO2)(EtOH)]

Authors
Hu, CH Englert, U
Citation
Ch. Hu et U. Englert, Bis(dimethylglyoximato-N,N ')(ethanol-O)nitrocobalt(III), [Co(Hdmg)(2)(NO2)(EtOH)], ACT CRYST E, 57, 2001, pp. m222-m223
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
6
Pages
m222 - m223
Database
ISI
SICI code
1600-5368(200106)57:<m222:B'[>2.0.ZU;2-D
Abstract
In the distorted octahedral title complex, [Co(NO2)-(C2H6O)(C4H7N2O2)(2)], the Co atom is coordinated to two chelating ligands in the equatorial plane , with nitro and ethanol groups occupying the axial positions. In addition to the asymmetric intramolecular hydrogen bridges between the equatorial li gands, strong intermolecular hydrogen bonds result in a pairwise arrangemen t of the molecules with respect to a crystallographic inversion center.