A bent two-coordinate silver(I) complex with 2,2 ',3,3 '-tetrahydro-4,4 '-dithia-1,1 '-binaphylidene

Authors
Wen, M Munakata, M Suenaga, Y Kuroda-Sowa, T Maekawa, M Yan, SG
Citation
M. Wen et al., A bent two-coordinate silver(I) complex with 2,2 ',3,3 '-tetrahydro-4,4 '-dithia-1,1 '-binaphylidene, ACT CRYST E, 57, 2001, pp. m246-m247
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
6
Pages
m246 - m247
Database
ISI
SICI code
1600-5368(200106)57:<m246:ABTSCW>2.0.ZU;2-C
Abstract
The Ag I complex of 2,2',3,3' -tetrahydro-4,4'-dithia-1,1'-binaphylidene (t tp) has been synthesized and its molecular structure determined as its PF6- salt, i.e. (2,2',3,3'-tetrahydro4,4'-dithia-1,1'--binaphylidene)silver(I) hexafluorophosphate, [Ag(C18H16S2)]PF6. The Ag-I ion has a distorted linear geometry comprised of the two S atoms of ttp, with an Ag-S distance of 2.4 889 (8) Angstrom and an S-Ag-S angle of 157.48 (4)degrees; the cation has t wofold symmetry. This coordination mode results in the formation of a nine- membered ring.