trans-bis(acetonitrile-N)tetraaquanickel(II) dibromide

Citation
T. Assoumatine et H. Stoeckli-evans, trans-bis(acetonitrile-N)tetraaquanickel(II) dibromide, ACT CRYST E, 57, 2001, pp. M179-M180
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
M179 - M180
Database
ISI
SICI code
1600-5368(200105)57:<M179:TD>2.0.ZU;2-F
Abstract
The structure of trans-[Ni(CH3CN)(2)(H2O)(4)]Br-2 has been determined at 15 3 K. The complex possesses C-i symmetry, with the Ni-II atom lying on an in version center. The Ni atom is coordinated to four water molecules in the e quatorial plane and to two trans acetonitrile molecules. In the crystal, a three-dimensional structure is formed by hydrogen bonding involving the lat tice Br- ions and the coordinated water molecules.