Bis(2,2 '-bipyridine-N,N ')dicyanoiron(III) nitrate

Citation
Rd. Poulsen et A. Hazell, Bis(2,2 '-bipyridine-N,N ')dicyanoiron(III) nitrate, ACT CRYST E, 57, 2001, pp. M186-M187
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
M186 - M187
Database
ISI
SICI code
1600-5368(200105)57:<M186:B''N>2.0.ZU;2-3
Abstract
The Fe atom of the title compound, [Fe(bipy)(2)(CN)(2)O](NO3) (bipy is 2,2' -bipyridine, C10H8N2), is octahedrally coordinated to the N atoms of the bi pyridines and to the C atoms of the cyanide groups which are cis to each ot her. The Fe-C distances are 1.922 (3) and 1.923 (2) Angstrom, and the Fe-N bonds trans to CN are 1.972 (2) and 1.973 (2) Angstrom and are longer than those cis to the CN groups, viz. 1.955 (2) and 1.962 (2) Angstrom. The bipy ridine groups are close to being planar, with N-C-C-N torsion angles of -2. 4 (3) and 1.6 (3)degrees, and bite angles of 81.43 (8) and 81.74 (8)degrees .