Bis(mu-diphenylthiophosphinito-S : P)bis[(eta(5)-cyclopentadienyl)nickel(II)]

Authors
Fun, HK Chantrapromma, S Razak, IA Zhang, QF Xin, XQ
Citation
Hk. Fun et al., Bis(mu-diphenylthiophosphinito-S : P)bis[(eta(5)-cyclopentadienyl)nickel(II)], ACT CRYST E, 57, 2001, pp. M190-M191
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
M190 - M191
Database
ISI
SICI code
1600-5368(200105)57:<M190:B:P>2.0.ZU;2-G
Abstract
The title compound, [(eta (5)-C5H5)Ni(S)PPh2](2) or [Ni-2(C5H5)(2)-(C12H10P S)(2)], consists of two (eta (5)-C5H5)Ni moieties bridged by the P and S at oms of two [Ph2P(S)](-) ligands, forming a nonplanar Ni-S-P-Ni-S-P twist-bo at heterocycle. The average Ni-P and Ni-S bond lengths are 2.1498 (6) and 2 .1983 (5) Angstrom, respectively.