A tetranuclear copper complex, [Cu-4(mu(3)-OH)(2)(mu(2)-OH)(2)(phen)(4)(H2O)(2)](NO3)(4)center dot 2H(2)O

Authors
Cui, CP Dai, JC Wu, LM Du, WX Wu, XT
Citation
Cp. Cui et al., A tetranuclear copper complex, [Cu-4(mu(3)-OH)(2)(mu(2)-OH)(2)(phen)(4)(H2O)(2)](NO3)(4)center dot 2H(2)O, ACT CRYST E, 57, 2001, pp. M198-M200
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
M198 - M200
Database
ISI
SICI code
1600-5368(200105)57:<M198:ATCC[>2.0.ZU;2-T
Abstract
The crystal structure of the title compound, diaquadi-mu (3)-hydroxo-di-(mu )2--hydroxo-tetraphenanthrolinetetracopper(II) tetranitrate dihydrate, [Cu- 4(OH)(4)(C10H8N2)(4)(H2O)(2)]-(NO3)(4). 2H(2)O, was determined by single-cr ystal X-ray diffraction. The tetranuclear copper structure has a chair form and each copper has a tetragonal pyramidal coordination geometry. The comp ound was synthesized by the hydro(solvo)thermal method and there is a fluor escence peak at 450 nm.