trans-dichlorobis(3,5-dimethylpyrazole-N)-bis(triphenylphosphine-P)ruthenium(II)

Citation
S. Chantrapromma et al., trans-dichlorobis(3,5-dimethylpyrazole-N)-bis(triphenylphosphine-P)ruthenium(II), ACT CRYST E, 57, 2001, pp. M207-M208
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
M207 - M208
Database
ISI
SICI code
1600-5368(200105)57:<M207:T>2.0.ZU;2-L
Abstract
In the title centrosymmetric Ru-II mononuclear complex, trans-Ru(PPh3)(2)(3 ,5-Me(2)pz)(2)Cl-2 (pz = pyrazole), [RuCl2(C5H7N2)(2)-(C18H15P)(2)], the Ru -II ion exhibits an octahedral coordination environment, consisting of the two trans P atoms of PPh3, the two trans N atoms of 3,5-Me(2)pz and the two trans Cl atoms. The 3,5-Me-2 pz ligands coordinate terminally to the centr al Ru-II ion.