N-(4,4-dimethoxy-1-oxo-1 lambda(6)-thianylidene)-4-methyl-1-benzenesulfonamide

Authors
Creaser, SP Pyke, SM Tiekink, ERT
Citation
Sp. Creaser et al., N-(4,4-dimethoxy-1-oxo-1 lambda(6)-thianylidene)-4-methyl-1-benzenesulfonamide, ACT CRYST E, 57, 2001, pp. O394-O395
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
5
Pages
O394 - O395
Database
ISI
SICI code
1600-5368(200105)57:<O394:NL>2.0.ZU;2-P
Abstract
In the title compound, C14H21NO5S2, the imine group belonging to the tosyla mide substituent occupies an axial position at the S atom of the thiane rin g; the latter adopts a chair conformation. The torsion angle C(Ph)-S(O-2)-N =S in the bridge between the two rings is -93.6 (2)degrees and the S-N=S bo nd angle is 122.15 (14)degrees.