Bis[3-hydroxy-4-methyl-2(3H)-thiazolethiolato-S-2,O]-bis(methanol-O)cobalt(II)

Authors
Citation
Ad. Bond et W. Jones, Bis[3-hydroxy-4-methyl-2(3H)-thiazolethiolato-S-2,O]-bis(methanol-O)cobalt(II), ACT CRYST E, 57, 2001, pp. m140-m142
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
4
Pages
m140 - m142
Database
ISI
SICI code
1600-5368(200104)57:<m140:B>2.0.ZU;2-M
Abstract
The structure of the title compound, [Co(C4H4NOS2)(2)(CH4O)(2)], has been d etermined at 180 (2) K. The molecule possesses (1) over bar point symmetry with the Co-II atom adopting a Jahn-Teller-distorted octahedral geometry. T he molecules are linked into chains by O-H . . .O hydrogen-bond interaction s involving the H atom of the coordinated methanol molecules.