(Benzylamine-N)(eta(5)-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate

Citation
Ja. Cabeza et al., (Benzylamine-N)(eta(5)-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate, ACT CRYST E, 57, 2001, pp. m162-m163
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
4
Pages
m162 - m163
Database
ISI
SICI code
1600-5368(200104)57:<m162:(>2.0.ZU;2-D
Abstract
The reaction of [RuCl(Cp)(PPh3)(2)] with Ag[BF4] in tetrahydrofuran, in the presence of benzylamine, leads to the mononuclear title compound [Ru(Cp)(H 2NCH2Ph)(PPh3)(2)]BF4, where Cp is cyclopentadienyl (C5H5). The Ru atom pre sents a pseudo-octahedral environment with the Cp ligand occupying three fa cial coordination sites, while the remaining coordination positions are occ upied by the P atoms of the two triphenylphosphine ligands and by the N ato m of the benzylamine ligand. The [BF4](-) counter-ion remains uncoordinated .