Ja. Cabeza et al., (Benzylamine-N)(eta(5)-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate, ACT CRYST E, 57, 2001, pp. m162-m163
The reaction of [RuCl(Cp)(PPh3)(2)] with Ag[BF4] in tetrahydrofuran, in the
presence of benzylamine, leads to the mononuclear title compound [Ru(Cp)(H
2NCH2Ph)(PPh3)(2)]BF4, where Cp is cyclopentadienyl (C5H5). The Ru atom pre
sents a pseudo-octahedral environment with the Cp ligand occupying three fa
cial coordination sites, while the remaining coordination positions are occ
upied by the P atoms of the two triphenylphosphine ligands and by the N ato
m of the benzylamine ligand. The [BF4](-) counter-ion remains uncoordinated
.