N-ethyldithiophthalimide, the first structure of a dithiophthalimide derivative

Citation
A. Meden et al., N-ethyldithiophthalimide, the first structure of a dithiophthalimide derivative, ACT CRYST E, 57, 2001, pp. o303-o304
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
4
Pages
o303 - o304
Database
ISI
SICI code
1600-5368(200104)57:<o303:NTFSOA>2.0.ZU;2-R
Abstract
The title compound, C10H9NS2, represents the first structurally studied der ivative of dithiophthalimide. The C=S bond lengths are 1.629 (3) and 1.637 (3) Angstrom; other geometric parameters are very close to the analogous va lues observed in the phthalimide structures. The least-square planes of the dithiophthalimide parts of the molecules in the crystal are parallel; thes e parts do not form any short contacts, leaving space for the ethyl groups pointing out of the plane [the 'out-of-plane torsion angles' C-N-C-C being equal to 90.7 (4) and -91.6 (4)degrees].