On the reaction of nickel(II) ions with thiolacetic acid

Authors
Mahmoudkhani, AH Langer, V
Citation
Ah. Mahmoudkhani et V. Langer, On the reaction of nickel(II) ions with thiolacetic acid, ACT CRYST E, 57, 2001, pp. M92-m94
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
M92 - m94
Database
ISI
SICI code
1600-5368(20010301)57:<M92:OTRONI>2.0.ZU;2-7
Abstract
An unexpected mononuclear nickel thiolate, bis(perthioacetato-S,S')nickel(I I), [Ni(C2H3S3)(2)], has been obtained by the reaction of Ni-II ions with t hiolacetic acid. It consists of a planar rectangular NiS4 unit. Weak hydrog en bonds of the type C-H . . . Ni form molecular ribbons along the a axis. Among the products, gamma -sulfur is also detected.