(Benzophenone imine-N)nonacarbonyl-dirhenium(0)(Re-Re)

Authors
Cabeza, JA del Rio, I Zuniga-Villarreal, N Garcia-Granda, S
Citation
Ja. Cabeza et al., (Benzophenone imine-N)nonacarbonyl-dirhenium(0)(Re-Re), ACT CRYST E, 57, 2001, pp. M130-M131
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
M130 - M131
Database
ISI
SICI code
1600-5368(20010301)57:<M130:(I>2.0.ZU;2-H
Abstract
The reaction of [Re-2 (CO)(10)] with benzophenone imine in dichloroethane, in the presence of Me3NO, leads to the binuclear title compound, nonacarbon yl(diphenylmethanimine-N)dirhenium(0)(Re-Re), [Re-2 (HN=CPh2)(CO)(9)]. Both Re atoms are in an octahedral environment. The HN=CPh2 ligand is attached to one of the metal atoms through the N atom, occupying an equatorial posit ion. The equatorial carbonyl ligands of each octahedral fragment are stagge red by 45 degrees.