(+)-(RR)-{mu-m-Phenylenedimethylenebis[tert-butyl-(phenyl)phosphine]}bis(borane)

Authors
Lebel, H Berthod, M Belanger-Gariepy, F
Citation
H. Lebel et al., (+)-(RR)-{mu-m-Phenylenedimethylenebis[tert-butyl-(phenyl)phosphine]}bis(borane), ACT CRYST E, 57, 2001, pp. o282-o284
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
3
Pages
o282 - o284
Database
ISI
SICI code
1600-5368(20010301)57:<o282:(>2.0.ZU;2-6
Abstract
The title compound, C28H42B2P2, (II), was synthesized with >95% enantiomeri c excess, and the relative and absolute configuration was determined. Both P atoms have distorted tetrahedral geometry, and the average B-P-C angle an d P-B distance are 112.7 (6)degrees and 1.910 (6) Angstrom, respectively.