Bis(triethanolamine-N,O,O ')nickel(II) bis(saccharinate)

Citation
Y. Topcu et al., Bis(triethanolamine-N,O,O ')nickel(II) bis(saccharinate), ACT CRYST E, 57, 2001, pp. m82-m84
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
2
Pages
m82 - m84
Database
ISI
SICI code
1600-5368(200102)57:<m82:B'B>2.0.ZU;2-4
Abstract
The structure of the title compound, [Ni(C6H15NO3)(2)](C7H4NO3S)(2), consis ts of a cationic [Ni(TEA)(2)](2+) and two anionic (SAC)(-) moieties (TEA is triethanolamine and SAC is the saccharinate anion). Two TEA ligands coordi nate to the NiII ion through four O atoms and two N atoms acting as trident ate ligands (N,O,O') in a distorted octahedral environment, with the bond d istances [d(Ni-O) = 2.078 (2) and 2.082 (2) Angstrom, and d(Ni-N) = 2.108 ( 2) Angstrom]. SAC anions participate in intermolecular hydrogen bonding wit h the hydroxyl H atoms of the TEA ligands to form a three-dimensional netwo rk.