Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum

Citation
Km. Anderson et al., Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum, ACT CRYST E, 57, 2001, pp. M419-m420
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
10
Pages
M419 - m420
Database
ISI
SICI code
1600-5368(200110)57:<M419:D>2.0.ZU;2-L
Abstract
The structure of the title compound, [Mo(eta (6)-C4Me4B2F2)(2) (CO)(2)], (I I), was determined by X-ray crystallography at 173 K and has two independen t molecules of (II) in the asymmetric unit. The six-membered diboracycles a re eta (6)-coordinated [Mo-C-alkene = 2.4157 (18)-2.6008 (19); Mo-B = 2.538 (2)-2.621 (2) Angstrom].