Citation
Ga. Van Albada et al., catena-poly[[dicyanamidobis(3-hydroxypyridine-N)-copper(II)]-mu-dicyanamido], ACT CRYST E, 57, 2001, pp. m421-m423
Citations number
25
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368
→ ACNP
Volume
57
Year of publication
2001
Part
10
Pages
m421 - m423
Database
ISI
SICI code
1600-5368(200110)57:<m421:C>2.0.ZU;2-A
Abstract
In the crystal structure of the title compound, [Cu-II {N(CN)(2)}(2) (C5H5N
O)(2)], the geometry around the copper(II) ion is distorted square pyramida
l, with the basal plane formed by the N atoms of two 3-hydroxypyridine mole
cules, one N atom of a bidentate dicyanamide anion and one N atom of a mono
dentate dicyanamide anion. The apical position is occupied by an N atom of
a bidentate dicyanamide anion, forming a one-dimensional polymeric chain.